Kinetics of fine wet grinding of zeolite in a steel ball mill in comparison to dry grinding   总被引：1，自引：0，他引：1  

A. Ozkan  M. Yekeler  M. Calkaya 《International Journal of Mineral Processing》2009,90(1-4):67-73

Batch wet grinding of zeolite was studied with emphasis on a kinetic study in a laboratory size steel ball mill of 200 mm diameter. The breakage parameters were determined by using the single sized feed fractions of − 850 + 600 µm, − 600 + 425 µm and − 425 + 300 µm for the zeolite samples. The S_i (specific rate of breakage) and B_i,j (primary breakage distribution) values were obtained for those feed size fractions in order to predict the product size distributions by simulation for comparison to the experimental data. The specific rates of breakage values for wet grinding in the first-order breakage region were higher than the dry values reported previously by a factor 1.7 at the same experimental conditions, but the primary breakage distribution (B_i,j) values were approximately the same. The simulations of the product size distributions of zeolite were in good agreement with the experimental data using a standard ball mill simulation program. The wet grinding of zeolite was subjected to slowing-down effect in the mill at 2 min of grinding, corresponding to an 80% passing size of about 400 µm. On the other hand, the slowing down effect in the dry grinding of zeolite was also seen at 4 min of grinding. In addition, effects of some operational parameters on dry and wet grinding of zeolite were determined by simulation using the breakage parameters obtained experimentally.  相似文献   

基于旋翼无人机观测的雾天和霾天VOCs垂直分布特征研究          下载免费PDF全文

刘若岚  刘端阳  袁淑杰  祖繁  吴泓  刘瑞翔 《大气科学学报》2023,46(5):655-666

为研究雾和霾天气下VOCs时空变化特征,于2020年11月19 日—2021年1月15日在江苏省东海国家气象观测站进行为期58 d的外场观测试验。利用自主研发的多旋翼无人机捕获2次辐射雾和2次霾天气过程,获得气温、气压、相对湿度、风向、风速、VOCs、O₃等7种要素100多条垂直廓线。结果表明:时间上,霾过程夜间VOCs体积浓度(0.225~0.253 ppm(parts per million, 1 ppm=10^-6))明显高于白天(0.191~0.205 ppm),雾形成前体积浓度(0.121~0.239 ppm)显著高于雾过程(0.056~0.209 ppm)。雾过程中VOCs体积浓度与雾强度变化相反,雾层高度与VOCs体积浓度剧烈变化高度一致,雾层(<200 m)中VOCs体积浓度(0.172~0.178 ppm)明显减小,显著低于雾形成前(0.195~0.240 ppm),雾层以上浓度变化大,雾结束后1 h内保持雾过程中分布特点。雾对逆温层中的水溶性污染物有清除作用,VOCs体积浓度和O₃质量浓度均下降。  相似文献   

The morphology and hydrology of small spring-dominated channels     

Ronald E. Griffiths  Diana E. Anderson  Abraham E. Springer   《Geomorphology》2008,102(3-4):511-521

Small, low order channels located in wet meadows along the Mogollon Rim of northern Arizona that receive the bulk of their flow from spring discharge exhibit a morphology that differs markedly from channels that receive the bulk of their flow from runoff. These small, spring-dominated channels generally have dense vegetation cover, vertical (or near vertical) banks with flat channel beds that are armored with clasts up to 60 mm. Clasts armoring the spring-dominated channels become mobile at 45 to 85% of the bankfull depth. The lack of fine-grained material in the bed of the spring-dominated channels reflects the small drainage size, lack of fine grain input from the spring, and winnowing affect of the consistent discharge. Minor amounts of large woody debris were present in some of the spring-dominated channels, however, unlike previous studies it does not appear to play a role in the spring-dominated channel morphology. Sinuosity values for spring-dominated channels averaged 1.19, while the average sinuosity values for the runoff-dominated channels, 1.08, were significantly lower. Measured width-to-depth ratios averaged 2.4 in the spring-dominated channels, much lower than the average ratio of 11.6 found for the runoff-dominated channels. The standard deviation of width-to-depth ratios was higher for runoff-dominated channels, reflecting a more variable channel profile. A third channel type, here referred to as hybrid channels, receive significant flow from both springs and runoff. These channels have characteristics that fall between spring-dominated and runoff-dominated channels.Elevation, gradient, organic matter content, and sediment grain size distribution of the wet meadows in which the channels are formed do not exhibit significant differences between channel types, suggesting that these factors are not responsible for the observed differences in channel morphologies. The major differences in controls on the channel morphology found between the spring-dominated and runoff-dominated channels are the discharge regime and the sediment input. The hydrology unique to the spring-dominated channels and the lack of fine-grained sediment input combine to create the observed differences.  相似文献   

The Annual Characteristics of Rainwater HCHO in Guiyang City,Southwest of China     

Xu Gang  Shao HongBo  Lee XinQing  Lv YingChun 《洁净——土壤、空气、水》2010,38(8):726-731

HCHO is ubiquitous and important chemical constitutes in the troposphere. The concentrations of the HCHO (aq) in the rainwater were measured in the Guiyang city, southeastern of China from May 2006 to April 2007 and 153 discrete samples were collected. Rainwater (N = 151) HCHO (aq) concentrations ranged from lower than method detection limit (MDL) to 40.2 µmol/L with a volume weighted mean value of 7.4 ± 8.8 µmol/L. The strong correlations between HCHO (aq) and HCOO^? (r = 0.69, n = 137), HCHO (aq) and nss‐ (r = 0.74, n = 137), HCHO (aq) and (r = 0.67, n = 137), HCHO (aq) and (r = 0.74, n = 133) suggest the significant influence of the anthropogenic input for the HCHO (aq) levels. The concentration levels of rainwater HCHO (aq) was inversely proportional to the amount of rainfall, indicating the below‐cloud process is the most important mechanism for rainwater HCHO (aq) scavenging processes. More than 70% of the HCHO (aq) wet deposition took place during the early stage of the rainfall. According to the air mass back‐trajectory analysis, the rainwater with industrial back‐trajectories coming from the north had the highest levels of HCHO (aq) while the rainwater with the green‐covered or marine back‐trajectories from the southeast had the lowest concentrations, and this indicate the HCHO (aq) originated from urban or industrial regions served as an important source of the rainwater. The annual HCHO (aq) wet deposition flux was calculated as 6.96 mmol/m² per year and the total deposition flux was estimated as 24.35 mmol/m² per year, 71.4% of which was dominated by dry deposition.  相似文献   

On the scavenging of SO2 by cloud and raindrops: II. An experimental study of SO2 absorption and desorption for water drops in air     

C. J. Walcek  H. R. Pruppacher  J. H. Topalian  S. K. Mitra 《Journal of Atmospheric Chemistry》1983,1(3):291-306

For the purpose of testing our previously described theory of SO₂ scavenging a laboratory investigation was carried out in the UCLA 33 m long rainshaft. Drops with radii between 250 and 2500 m were allowed to come to terminal velocity, after which they passed through a chamber of variable length filled with various SO₂ concentrations in air. After falling through a gas separating chamber consisting of a fluorocarbon gas the drops were collected and analyzed for their total S content in order to determine the rate of SO ₂ absorption.The SO₂ concentration in air studied ranged between 1 and 60% (v). Such relatively large concentrations were necessary due to the short times the drops were exposed to SO₂ in the present setup. The present experimental results were therefore not used to simulate atmospheric conditions but rather to test our previously derived theory which is applicable to any laboratory or atmospheric condition. Comparison of our studies with the results from our theory applied to our laboratory conditions led to predicted values for the S concentration in the drops which agreed well with those observed if the drops had radii smaller than 500 m. In order to obtain agreement between predicted and observed S concentrations in larger drops, an empirically derived eddy diffusivity for SO₂ in water had to be included in the theory to take into account the effect of turbulent mixing inside such large drops.In a subsequent set of experiments, drops initially saturated with S (IV) were allowed to fall through S-free air to determine the rate of SO ₂ desorption. The results of these studies also agreed well with the results of our theoretical model, thus justifying the reversibility assumption made in our theoretical models.In a final set of experiments, the effects of oxidation on SO₂ absorption was studied by means of drops containing various amounts of H₂O₂. For comparable exposure times to SO₂, the S concentration in drops with H₂O₂ was found to be up to 10 times higher than the concentration in drops in which no oxidation occurred.  相似文献   

Determination of the Tropospheric Hydroxyl Radical by Liquidphase Scrubbing and HPLC: Preliminary Results     

Xiaohui Chen  Kenneth Mopper 《Journal of Atmospheric Chemistry》2000,36(1):81-105

A preliminary study was carried out toexamine the feasibility of measuring tropospherichydroxyl radicals (OH) by liquidphase scrubbing andhigh performance liquid chromatography (HPLC). Thepotential advantages of this approach are itssimplicity, portability, and low expense. Thesampling system employs glass bubblers to trapatmospheric OH into a buffered solution of salicylicacid (o-hydroxybenzoic acid, OHBA). Rapidreaction of OH with OHBA produces a stable fluorescentproduct, 2,5-dihydroxybenzoic acid (2,5-DHBA), whichis determined by reverse-phase HPLC and fluorescencedetection. Our preliminary field results indicatethat this method is most suitable for OH measurementsin clean tropospheric air, where interferences fromother atmospheric species appear to be negligible orminor relative to polluted air. In clean air, thesampling period is about 45–90 minutes, which yieldsa detection limit of approximately 3–6 ×10⁵ radicalscm^-3. During an OHintercomparison experiment at the Caribou samplingsite in Colorado, our liquidphase scrubber method wascompared with the ion-assisted mass spectrometry (MS)method. Our results were within the same range asthose of the ion-assisted MS method (1–5 ×10⁶ radicals cm^-3) within our precision atthat time (about ±30–50%). Preliminary testsin Pullman, WA indicated that the method might alsofunction in moderately polluted air by acidifying thescrubbing solution or by adding a scavenger tosuppress interferences. In Pullman, mid-day OHconcentrations were usually in the range of 2–20 ×10⁶ radicals cm^-3. Nighttime OHconcentrations were always low, either at or slightlyabove the detection limit.  相似文献   

On the scavenging of gaseous nitrogen compounds by large and small rain drops I. A wind tunnel and theoretical study of the uptake and desorption of NH3 in the presence of CO2     

A. U. Hannemann  S. K. Mitra  H. R. Pruppacher 《Journal of Atmospheric Chemistry》1995,21(3):293-307

An experimental study has been carried out in the Mainz vertical wind tunnel to determine the rate at which NH₃ in the presence of CO₂ is absorbed by freely suspended water drops. The experimental uptake rates were found to be in good agreement with the rates predicted by the Kronig-Brink convective diffusion model and, for gas concentrations in the ppbv range also by the model in which it is assumed that the absorbed gas is well mixed inside the drop (henceforth called well mixed model). The same conclusion was shown to apply also to the desorption of NH₃ from a drop previously exposed to NH₃. The latter result is in contrast to the desorption of SO₂ which must be described by a model which accounts for the diffusion of the species inside the drop. Comparison of our experimental results with theory show further that the uptake of NH₃ in presence of CO₂ is significantly overestimated if the slow reaction CO_2(aq)+H₂OHCO ₃ ^– +H⁺ is neglected in the theoretical computation.  相似文献   

Thorium sorption in the marine environment: Equilibrium partitioning at the hematite/water interface,sorption/desorption kinetics and particle tracing     

Matthew S. Quigley  Bruce D. Honeyman  Peter H. Santschi 《Aquatic Geochemistry》1995,1(3):277-301

Thorium(IV) sorption onto hematite (-Fe₂O₃) was examined as a function of pH and ionic strength. Sorption behaved Langmuirian over an eleven order of magnitude range in adsorption densities, : 10^–12 to 10^–1 moles Th sorbed per mole hematite sites, indicating that the overall free energy of Th adsorption is independent of adsorption density. Modeling of Th sorption was conducted with the Triple Layer Model of Davis and Leckie; reactions considered included solution-phase hydroxy and carbonato complexes of thorium, and carbonate/hematite surface complexes. The entire Th sorption isotherm can be modeled with a single surface complex formation reaction

相似文献    29. On the scavenging of gaseous nitrogen compounds by large and small rain drops: II. Wind tunnel and theoretical studies of the simultaneous uptake of NH3, SO2 and CO2 by water drops      A. U. Hannemann  S. K. Mitra  H. R. Pruppacher 《Journal of Atmospheric Chemistry》1996,24(3):271-284 An experimental investigation of the simultaneous absorption of NH3 and SO2 from the ambient atmosphere by freely falling water drops has been carried out in the Mainz vertical wind tunnel. The experimental results were found to be in good agreement with the results derived from computations with the Kronig-Brink convective diffusion model and also with a model which assumes a drop to be well mixed at all times. Encouraged by this agreement, these computation schemes for the uptake of gas by single drops where incorporated in a pollution washout model with realistic SO2, NH3 and CO2 gas profiles. This model allows an entire raindrop size distribution to fall through a gas layer. The results of this plume-model show that the SO2 uptake is strongly dependent on the NH3 concentration in the atmosphere and on the rainrate. We also find that the small drops contribute more towards the washout of these gases. In the case of simultaneous presence of NH3 and SO2, desorption of these gases is negligible.  相似文献    30. Assessment of stone crab (Lithodidae) density on the South Georgia slope using baited video cameras   总被引：2，自引：0，他引：2   Collins  M. A.; Yau  C.; Guilfoyle  F.; Bagley  P.; Everson  I.; Priede  I. G.; Agnew  D. 《ICES Journal of Marine Science》2002,59(2):370-379   相似文献    [首页] « 上一页 [1] [2] 3 [4] [5] [6] [7] [8] [9] [10] [11] 下一页 » 末  页»